The template files can be found within the /plugins/dk-pdf/templates/
directory.
Override templates in Theme
You can customize DK PDF template files in an upgrade safe way through overrides. Simply copy the desired templates into a directory within your theme named /dkpdf, keeping the same file structure.
Example:
Copy plugins/dk-pdf/templates/dkpdf-index.php to themes/your-theme/dkpdf/dkpdf-index.php
Override templates in Child Theme
DK PDF allows override templates in Child Themes too.
Example:
Copy plugins/dk-pdf/templates/dkpdf-index.php to themes/your-child-theme/dkpdf/dkpdf-index.php
More info about Child Themes (WordPress Theme Handbook)